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- W2161170050 abstract "Das stabilste der drei möglichen Strukturisomere des Corrols ist laut Theorie das Isocorrol, für das die Titelverbindung 1 eine Modellverbindung ist. Einen präparativen Zugang zu 1 eröffnet die reduktive Kupplung des entsprechenden α‐ω‐Tetrapyrroldialdehyds nach McMurry. Das Isocorrolderivat 1 vermag analog zu Corrol Metallionen in höheren Oxidationszuständen zu stabilisieren. Ein Beispiel dafür ist der Cu III ‐Komplex 2 , der als Zwischenstufe auf dem Wege zum 9‐Formyloctaethylisocorrol isoliert wurde. magnified image" @default.
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- W2161170050 date "1997-12-01" @default.
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- W2161170050 title "Kontrahierte Porphyrine: Octaethylisocorrol" @default.
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- W2161170050 doi "https://doi.org/10.1002/ange.19971092313" @default.
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