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- W2161222061 abstract "Dodecaborate anions of the type B12X12(2-) and B12X11Y(2-) (X=H, Cl, Br, I and Y=OH, SH, NH3(+), NR3(+)) form strong (K(a) up to 10(6) L mol(-1), for B12Br12(2-)) inclusion complexes with γ-cyclodextrin (γ-CD). The micromolar affinities reached are the highest known for this native CD. The complexation exhibits highly negative enthalpies (up to -25 kcal mol(-1)) and entropies (TΔS up to -18.4 kcal mol(-1), both for B12I12(2-)), which position these guests at the bottom end of the well-known enthalpy-entropy correlation for CDs. The high driving force can be traced back to a chaotropic effect, according to which chaotropic anions have an intrinsic affinity to hydrophobic cavities in aqueous solution. In line with this argument, salting-in effects revealed dodecaborates as superchaotropic dianions." @default.
- W2161222061 created "2016-06-24" @default.
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- W2161222061 creator A5086761988 @default.
- W2161222061 date "2015-05-07" @default.
- W2161222061 modified "2023-10-18" @default.
- W2161222061 title "Water Structure Recovery in Chaotropic Anion Recognition: High-Affinity Binding of Dodecaborate Clusters to γ-Cyclodextrin" @default.
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- W2161222061 doi "https://doi.org/10.1002/anie.201412485" @default.
- W2161222061 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4510780" @default.
- W2161222061 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25951349" @default.
- W2161222061 hasPublicationYear "2015" @default.
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