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- W2161250488 abstract "Authors describe the network structure of octadecylacrylate (ODA)-co-acrylic acid (AA) cross-linked with divinyl benzene (DVB). Crosslinked xerogels comprised of ODA/AA, with ODA molar composition ranging from 50 to 90%, were synthesised by radical initiation copolymerisation in different concentrations (1–10%) of DVB utilising either bulk or suspension techniques in two solvents. Atomic force microscopy images of the xerogels reveal a variety of porous morphologies. The average molecular weight between the cross-links and polymer-toluene interaction parameter of xerogels were determined from swelling measurements. The efficiency of DVB as a cross-linking agent for ODA/AA was also determined. An increase of concentration of AA in the copolymers enhances the thermal stability of the copolymers at elevated temperatures determined by thermogravimetric analysis (TGA). Moreover, the increase in AA concentration increases the average molecular weight between cross-links and thus enhances swelling of the copolymer by toluene; this is true for any of our copolymerisation procedures." @default.
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- W2161250488 date "2015-05-12" @default.
- W2161250488 modified "2023-10-18" @default.
- W2161250488 title "Network and swelling parameters of cross-linked octadecylacrylate-co-acrylic acid copolymers based on divinyl benzene cross-linker" @default.
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- W2161250488 doi "https://doi.org/10.1179/1433075x15y.0000000022" @default.
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