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- W2161532850 abstract "The new semirigid exo-bidentate ligand incorporating furfurysalicylamide terminal groups, namely, 1,4-bis{[(2′-furfurylaminoformyl)phenoxyl]methyl}-2,5-bismethylbenzene (L) was synthesized and used as building blocks for constructing lanthanide coordination polymers with luminescent properties. The series of lanthanide nitrate complexes have been characterized by elemental analysis, IR spectroscopy, and X-ray diffraction analysis. The semirigid ligand L, as a bridging ligand, reacts with lanthanide nitrates forming three distinct structure types: chiral noninterpenetrated two-dimensional (2D) honeycomblike (6,3) (hcb, Schläfli symbol 63, vertex symbol 6 6 6) topological network as type I, 1D zigzag chain as type II and 1D trapezoid ladder-like chain as type III. The structural diversities indicate that lanthanide contraction effect played significant roles in the structural self-assembled process. The luminescent properties of EuIII, TbIII and DyIII complexes are discussed in detail. Due to the good match between the lowest triplet state of the ligand and the resonant energy level of the lanthanide ion, the lanthanide ions in EuIII, TbIII and DyIII complexes can be efficiently sensitized by the ligand." @default.
- W2161532850 created "2016-06-24" @default.
- W2161532850 creator A5007338600 @default.
- W2161532850 creator A5021564732 @default.
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- W2161532850 creator A5036626129 @default.
- W2161532850 creator A5042221113 @default.
- W2161532850 creator A5046689089 @default.
- W2161532850 date "2014-10-01" @default.
- W2161532850 modified "2023-09-26" @default.
- W2161532850 title "Lanthanide coordination polymers: Synthesis, diverse structure and luminescence properties" @default.
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- W2161532850 doi "https://doi.org/10.1016/j.jssc.2014.06.025" @default.