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- W2161584259 abstract "ABSTRACT A supported liquid membrane has been used to dissolve selectively copper oxalate from a suspension of copper, calcium and cadmium oxalate, which have low, similar solubilities. 2-Hydroxy-5-nonyl-acetophenone oxime (HX) dissolved in kerosene was used as a carrier for copper transport from the suspension to the stripping solution. A mathematical model of the copper permeation is presented. The model takes into account the dissolution kinetics of CuC204-1/2H20, the diffusion of copper ions through an aqueous stagnant layer, the chemical reaction at the aqueous/membrane interface, and the diffusion of the CuX2 complex in the membrane. The model fits the experimental data well with a unique parameter set, except for the transport from an acetate buffered system, for which a lower rate constant for the reaction at the membrane interface had to be assumed. In a separate set of experiments the dissolution of copper oxalate hemihydrate in water was found to be surface reaction controlled." @default.
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- W2161584259 date "1996-07-01" @default.
- W2161584259 modified "2023-09-26" @default.
- W2161584259 title "SELECTIVE DISSOLUTION OF COPPER OXALATE USING SUPPORTED LIQUID MEMBRANES" @default.
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- W2161584259 doi "https://doi.org/10.1080/07366299608918364" @default.
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