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- W2161665806 abstract "Tricyclodecadienone epoxides 5 do not form an enolate on treatment with lithium diisopropyl amide. but instead undergo an unusual stereoselective β-hydride transfer leading to alcohols 6. The same type of epoxy endo-alcohol was obtained from parent epoxy ketone 5 on reaction with metal hydrides and organolithium reagents. These alcohols readily undergo an intramolecular epoxide migration by a Payne-type rearrangement, to give endo-epoxides 9." @default.
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- W2161665806 date "1991-06-01" @default.
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- W2161665806 title "Tricyclo[5.2.1.02,6]decadienone epoxides: rigid, highly congested α,β-epoxycyclopentanones with distinctive chemical behavior." @default.
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- W2161665806 doi "https://doi.org/10.1016/0040-4039(91)80707-d" @default.
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