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- W2161831254 abstract "Vertices, edges, and faces—in other words, the whole periphery of the Th6 octahedron in the title compound—are covered with Br and H atoms. The structure is novel in that the H atoms are not bonded interstitially but rather from “outside” to the cluster core, as shown by neutron diffraction of the perdeuterated compound (see the picture on the right; ). If the metal–metal bonds in the cluster are described qualitatively by eight closed three-center two-electron bonds directed toward the middle of the faces of the octahedron, it is clearly seen that seven of these bonds are stabilized by the additional electrons of the H atoms at the centers of the faces." @default.
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- W2161831254 date "1991-01-01" @default.
- W2161831254 modified "2023-10-14" @default.
- W2161831254 title "Th6Br15H7—Stabilization of a Th6Br12 Cluster by Seven Hydrogen Atoms" @default.
- W2161831254 doi "https://doi.org/10.1002/anie.199101011" @default.
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