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- W2162063675 abstract "VO(IV), Ni(II) and Cu(II) complexes of the asymmetric Schiff base [(HOC 6 H 3 (OCH 3 )C(C 6 H 5 ):N(CH 2 CH 2 )N:C(CH3)CH:C(C 6 H 5 )OH)], and their heteroleptic analogues with triphenyl phosphine and 2,2’-bipyridine have been synthesized and characterized by elemental analyses, conductance, magnetic, infrared and electronic spectral measurements. The ligand is tetradentate coordinating via the imine N and enolic O atoms. The Ni(II) and Cu(II) complexes adopt a four coordinate square planar geometry, the VO(IV) complex is five coordinate square-pyramidal and the heteroleptic complexes are 6-coordinate, octahedral. The assignment of geometry is collaborated by magnetic moments and electronic spectra measurements. The compounds are non-electrolyte in nitromethane and are magnetically dilute." @default.
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- W2162063675 date "2008-01-01" @default.
- W2162063675 modified "2023-10-17" @default.
- W2162063675 title "Syntheses and Characterization of Some Tetradentate Schiff-Base Complexes and Their Heteroleptic Analogues" @default.
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- W2162063675 doi "https://doi.org/10.1155/2008/654054" @default.
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