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- W2162187401 abstract "The [2+2+2] cyclotrimerization of 1-isoquinolinyl-1,7-octadiyne with benzonitrile catalyzed by CpCo(CO)2 opened a new pathway for a synthesis of unsymmetrical axially chiral bipyridine N,N′-dioxides. The N,N′-dioxide 3a was found to be highly catalytically active and enantioselective for the asymmetric allylation of aldehydes with allyltrichlorosilane. The allylation took place with even 1 % of the catalyst with an enantioselectivity up to 87 % ee." @default.
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- W2162187401 date "2007-04-02" @default.
- W2162187401 modified "2023-10-03" @default.
- W2162187401 title "A Simple Approach to Unsymmetric Atropoisomeric BipyridineN,N′-Dioxides and Their Application in Enantioselective Allylation of Aldehydes" @default.
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- W2162187401 doi "https://doi.org/10.1002/adsc.200600400" @default.
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