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• W2162216076 abstract "Sorbic acid (trans,trans-hexadienoic acid) was developed as a probe for the quantification of the formation rate, overall solution scavenging rate and steady-state concentrations of triplet-excited states of organic compounds. The method was validated against literature data for the quenching rate constant of triplet benzophenone by tyrosine obtained by laser flash photolysis and by Stern-Volmer plots of phosphorescence quenching. In contrast to these methods, the probe method does not require knowledge of the optical properties of triplets to monitor their quenching. Moreover, the probe method permits simultaneous quantification of triplet formation, quenching and steady-state concentrations during illumination of complex chromophore mixtures, such as natural organic matter (NOM), with polychromatic light >315 nm. Application of the method to de-aerated Suwannee River NOM illuminated with polychromatic light (315-430 nm) resulted in a triplet quantum yield of 0.062." @default.
• W2162216076 created "2016-06-24" @default.
• W2162216076 creator A5030115450 @default.
• W2162216076 creator A5045123804 @default.
• W2162216076 creator A5057541225 @default.
• W2162216076 date "2011-12-01" @default.
• W2162216076 modified "2023-10-16" @default.
• W2162216076 title "Sorbic acid as a quantitative probe for the formation, scavenging and steady-state concentrations of the triplet-excited state of organic compounds" @default.
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• W2162216076 doi "https://doi.org/10.1016/j.watres.2011.09.048" @default.
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