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• W2162238483 abstract "Hydrozirconation of 1-hexyne, the addition to in situ prepared N -acyliminium species, and ring-closing metathesis (RCM) were key steps in the preparation of a tricyclic isoindolinone scaffold. An unusual alkene isomerization process during the RCM was identified and studied in some detail. Chemical diversification for library synthesis was achieved by a subsequent alkene epoxidation and zinc-mediated aminolysis reaction. The resulting library products provided selective hits among a large number of high-throughput screens reported in PubChem, thus illustrating the utility of the novel scaffold." @default.
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• W2162238483 date "2012-07-13" @default.
• W2162238483 modified "2023-10-05" @default.
• W2162238483 title "Synthesis of a library of tricyclic azepinoisoindolinones" @default.
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• W2162238483 doi "https://doi.org/10.3762/bjoc.8.120" @default.
• W2162238483 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3458725" @default.
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