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- W2162273142 abstract "In this work, thin films of phase-pure Cu2ZnSnS4 (CZTS) were developed from a stack of binary metal sulfides by post-deposition thermal processing. The precursor stack SnS/Cu/ZnS was grown by sequential electrodeposition of SnS and Cu layers followed by thermal evaporation of ZnS layer. The transformation from binary/ternary composition to phase-pure CZTS was studied using different experimental tools such as X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The TEM images revealed the formation of tetragonal crystals with interplanar spacing 0.312 nm. Raman spectra of the films confirmed that annealing at 550°C for 30 min under N2/S ambient resulted in the formation of phase-pure CZTS film. The bandgap estimated from the optical transmittance and reflectance spectra showed a direct transition at 1.59 eV. The films are photosensitive and the photo electrochemical measurements showed the p-type conductivity of the films." @default.
- W2162273142 created "2016-06-24" @default.
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- W2162273142 date "2015-01-01" @default.
- W2162273142 modified "2023-10-13" @default.
- W2162273142 title "Structural Evolution of Multilayer SnS/Cu/ZnS Stack to Phase-Pure Cu<sub>2</sub>ZnSnS<sub>4</sub>Thin Films by Thermal Processing" @default.
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- W2162273142 doi "https://doi.org/10.1149/2.0171503jss" @default.
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