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• W2162279025 abstract "Abstract The first regiodivergent oxyboration of unactivated terminal alkenes is reported, using copper alkoxide as a catalyst, bis(pinacolato)diboron [(Bpin) 2 ] as a boron source, and (2,2,6,6‐tetramethylpiperidin‐1‐yl)oxyl (TEMPO) as an oxygen source. The reaction is compatible with various functional groups. Two regioisomers are selectively produced by selecting the appropriate ligands on copper. The products may be used as a linchpin precursor for various other functionalizations, and net processes such as carbooxygenation, aminooxygenation, and dioxygenation of alkenes can be achieved after CB bond transformations. Mechanistic studies indicate that the reaction involves the following steps: 1) Transmetalation between CuO t Bu and (Bpin) 2 to generate a borylcopper species; 2) regiodivergent borylcupration of alkenes; 3) oxidation of the thus‐generated CCu bond to give an alkyl radical; 4) trapping of the resulting alkyl radical by TEMPO." @default.
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• W2162279025 date "2015-09-17" @default.
• W2162279025 modified "2023-10-16" @default.
• W2162279025 title "Copper‐Catalyzed Oxyboration of Unactivated Alkenes" @default.
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• W2162279025 doi "https://doi.org/10.1002/chem.201503329" @default.
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