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• W2162279274 endingPage "11301" @default.
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• W2162279274 abstract "The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ(3)-iodanes. Here, we describe an alternative metal-free α-arylation using ArI(O2CCF3)2 as the source of a 2-iodoaryl group. The reaction is applicable to activated ketones, such as α-cyanoketones, and works with substituted aryliodanes. This formal C-H functionalization reaction is thought to proceed through a [3,3] rearrangement of an iodonium enolate. The final α-(2-iodoaryl)ketones are versatile synthetic building blocks." @default.
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• W2162279274 date "2014-09-04" @default.
• W2162279274 modified "2023-10-16" @default.
• W2162279274 title "An Alternative to the Classical α-Arylation: The Transfer of an Intact 2-Iodoaryl from ArI(O₂CCF₃)₂" @default.
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• W2162279274 doi "https://doi.org/10.1002/anie.201405982" @default.
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