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- W2162405759 abstract "Vernetzung und Oxidation sind Konkurrenzreaktionen bei der Bestrahlung von Polyethylen an Luft. Als Kettenreaktion ist die Oxidation auch bei der Elektronenbestrahlung nicht zu vernachlässigen, insbesondere wenn es sich um dünnwandiges Bestrahlungsgut handelt. HDPE ist bei Bestrahlung infolge höherer Stabilität der Radikale und Postoxidation sauerstoffempfindlicher als LDPE. Ausgehend von den bekannten Mechanismen der Strahlenoxidation werden die Bildung und der Zerfall der Peroxyradikale quantitativ beschrieben. Crosslinking and oxidation are competitive reactions during and after irradiation of polyethylene in air. The oxidation reaction cannot be neglected in thin-walled electron irradiated materials, especially because it is a chain reaction. On irradiation HDPE is more sensitive to oxygen than LDPE due to the higher stability of radicals and postoxidation in HDPE. Formation and decay of peroxy radicals are described quantitatively, taking into account the well-known mechanism of radiation oxidation." @default.
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- W2162405759 date "1985-09-01" @default.
- W2162405759 modified "2023-09-25" @default.
- W2162405759 title "Vernetzung und Oxidation bei der Elektronenbestrahlung von Polyethylenfolien" @default.
- W2162405759 doi "https://doi.org/10.1002/actp.1985.010360910" @default.
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