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- W2162406543 endingPage "6901" @default.
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- W2162406543 abstract "2,3-trans-carbamate- and -carbonate-carrying pyranosides were very easily anomerised from the β to the α direction in the presence of a Lewis acid compared to other pyranosides. This reaction is caused by endocyclic cleavage of the pyranosides. Evidence for endocyclic cleavage of conformationally restricted pyranosides in the chair form was obtained by intra- and intermolecular Friedel–Crafts reactions, chloride addition, and reduction of the generated cation. On the other hand, pyranosides with the distorted conformation were never cleaved in an endocyclic manner." @default.
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- W2162406543 date "2009-07-13" @default.
- W2162406543 modified "2023-09-27" @default.
- W2162406543 title "Evidence for Endocyclic Cleavage of Conformationally Restricted Glycopyranosides" @default.
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- W2162406543 doi "https://doi.org/10.1002/chem.200900064" @default.
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