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- W2162488648 abstract "The reported ability of chiral phosphonamide 1 to effect the enantioselective opening of meso epoxides with silicon tetrachloride has not withstood experimental verification by Denmark's group. Having reexamined the ring-opening of cyclooctene oxide (see scheme), Denmark and co-workers found a serious discrepancy between their results (81–83 % recovery of the epoxide and an essentially racemic product) and those reported by Buono et al. (77 % yield and >99 % ee)." @default.
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- W2162488648 date "2001-06-18" @default.
- W2162488648 modified "2023-09-30" @default.
- W2162488648 title "Beneficial Effect of ortho-Methoxy Groups in the Asymmetric Ring Opening of meso Epoxides with Silicon Tetrachloride Catalyzed by Chiral ortho-Methoxyphenyldiazaphosphonamide Lewis Bases Response to the Communication by G. Buono et al." @default.
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- W2162488648 doi "https://doi.org/10.1002/1521-3773(20010618)40:12<2255::aid-anie2255>3.0.co;2-3" @default.
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