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• W2162587953 startingPage "320" @default.
• W2162587953 abstract "Optically pure difluorolactates and trichlorolactates were prepared and their crystal structures were determined and compared with those of trifluorolactates. One-dimensional hydrogen bonding networks of these compounds involve infinite OH⋯OH, OH⋯OC, and C–H⋯OC hydrogen bonds. The crystal structure of a single-headed difluorolactate showed a weak intermolecular C–H⋯F hydrogen bond between difluoromethyl (CF2H) groups, leading to a one-dimensional C–H⋯F chain as a hydrogen bonding motif of the CF2H group. In the case of trichlorolactates, the steric effect of the trichloromethyl group on the hydrogen bonding system was revealed. Two-dimensional hydrogen bonding networks by double-headed trifluorolactates, difluorolactate and trichlorolactate provided isomorphic layered crystal structures." @default.
• W2162587953 created "2016-06-24" @default.
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• W2162587953 date "2006-01-01" @default.
• W2162587953 modified "2023-09-27" @default.
• W2162587953 title "Isomorphic supramolecular structures via one-dimensional hydrogen bonding motifs in crystals of chiral difluorolactates, trichlorolactates and trifluorolactates" @default.
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• W2162587953 doi "https://doi.org/10.1039/b600325g" @default.
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