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• W2162610608 abstract "Under the superposition approximation, the Kirkwood-Salsburg integral equation for the radial distribution function is expressed as a power series in the density, and the coefficients gk (x) in this series are compared with the exact quantities. It is found that, unlike the Kirkwood and the Born-Green-Yvon theories, this formalism provides g 1(x) and g 2(x) (and consequently the first four virial coefficients) correctly. Numerical values of g 3(x) and of the fifth virial coefficient for molecules interacting according to the Gaussian, rigid spherical, and square-mound potentials are presented. Comparisons between our results and those of other theoretical treatments are also given." @default.
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• W2162610608 date "1968-01-01" @default.
• W2162610608 modified "2023-09-27" @default.
• W2162610608 title "On the superposition approximation and the Kirkwood-Salsburg integral equation" @default.
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• W2162610608 doi "https://doi.org/10.1080/00268976800100391" @default.
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