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- W2162776734 abstract "The Raman line shapes of three symmetric modes ν1, ν3 and ν4 have been measured in liquid dichloromethane as a function of pressure from 1 bar to 3 kbar and of temperature from 183 to 363 K. The reorientation relaxation times are found to increase with higher pressures and to decrease with increasing temperatures. The isotropic half-width of the ν4 band behaves untypically, varying only insignificantly throughout the temperature and pressure range studied. The differences in frequency between the polarized and depolarized bands are also determined. The dipolar coupling mechanism is applied to interpret the effects observed." @default.
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- W2162776734 date "1981-12-01" @default.
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- W2162776734 title "Temperature and pressure Raman study of molecular motions in liquid CH2Cl2" @default.
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- W2162776734 doi "https://doi.org/10.1002/jrs.1250110604" @default.
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