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• W2162782324 abstract "The adsorption of nitrogen in a collection of spheres that touch or merge in a sintering-like manner is modeled using a Derjaguin–Broeckhof–de Boer approach. The proposed model accounts for both positive curvature effects and for capillary condensation at the contact between two spheres. A methodology is proposed to fit the P/P0>0.4 adsorption region with the coordination number of the spheres as the only adjustable parameter. The use of the model is illustrated on a series of silica aerogels. The suitability of various standard isotherms needed for the modeling is also discussed." @default.
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• W2162782324 date "2007-10-01" @default.
• W2162782324 modified "2023-09-23" @default.
• W2162782324 title "Positive curvature effects and interparticle capillary condensation during nitrogen adsorption in particulate porous materials" @default.
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• W2162782324 doi "https://doi.org/10.1016/j.jcis.2007.05.072" @default.
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