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- W2162990364 abstract "A new μ-oxo diiron(III) complex of the lithium salt of the pyridine-based unsymmetrical ligand 3-[(3-{[bis(pyridin-2-ylmethyl)amino]methyl}-2-hydroxy-5-methylbenzyl)(pyridin-2-ylmethyl)amino]propanoate (LiDPCPMPP), [Fe2(μ-O)(LiDPCPMPP)2](ClO4)2, has been synthesized and characterized. The ability of the complex to catalyze oxidation of several alkanes and alkenes has been investigated by using CH3COOH/H2O2 (1:1) as an oxidative system. Moderate activity in cyclohexane oxidation (TOF = 33 h–1) and good activity in cyclohexene oxidation (TOF = 72 h–1) were detected. Partial retention of configuration (RC = 53 %) in cis- and trans-1,2-dimethylcyclohexane oxidation, moderate 3°/2° selectivity (4.1) in adamantane oxidation, and the observation of a relatively high kinetic isotope effect for cyclohexane oxidation (KIE = 3.27) suggest partial metal-based oxidation, probably in tandem with free-radical oxidation. Low-temperature UV/Vis spectroscopy and mass spectrometric studies in the rapid positive detection mode indicate the formation of a transient peroxido species, [Fe2(O)(O2)(LiDPCPMPP)2]2+, which might be an intermediate in the metal-based component of the oxidation process." @default.
- W2162990364 created "2016-06-24" @default.
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- W2162990364 date "2015-07-01" @default.
- W2162990364 modified "2023-10-17" @default.
- W2162990364 title "Catalytic Oxidation of Alkanes and Alkenes by H <sub>2</sub> O <sub>2</sub> with a μ‐Oxido Diiron(III) Complex as Catalyst/Catalyst Precursor" @default.
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- W2162990364 doi "https://doi.org/10.1002/ejic.201500576" @default.
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