Matches in SemOpenAlex for { <https://semopenalex.org/work/W2163118625> ?p ?o ?g. }
- W2163118625 abstract "Treatment of Pd(PPh 3 ) 4 with N,N-dimethylthiocarbamoyl chloride, Me 2 NC(=S)Cl, in dichloromethane at -20 °C produces complex [Pd(PPh 3 ) 2 (η 1 -SCNMe 2 )(Cl)] (1). In solution state, complex 1 shows the intramolecular dissociation of the chloride or intermolecular dissociation of the triphenylphosphine ligands to form η 2 -thiocarbamoyl complex [Pd(PPh 3 ) 2 (η 2 -SCNMe 2 )][Cl] (2) or the bridging η 2 -thiocarbamoyl dipalladium complex [Pd(PPh 3 )Cl] 2 (μ,η 2 -SCNMe 2 ) 2 (3). Treatment of 1 with MeOCS 2 K yields [Pd(PPh 3 ){η 1 -C(SMe)(NMe 2 )}(η 2 -S2CO)] (5a). The Fischer-type carbene-complex 5a is formed via methyl migration of the methyldithiocarbonate to thiocarbamoyl ligand. Complex 1 reacts with EtOCS 2 K resulting in the formation of η 2 -dithiocarbonate complex [Pd(PPh 3 )(η 1 -SCNMe 2 )(η 2 -S 2 COEt)] (4b) and carbene-complex [Pd(PPh 3 ){η 1 -C(SEt)(NMe 2 )}(η 2 -S 2 CO)] (5b) with ratios of 10:1 from the integration of 3 1 P{ 1 H} NMR spectra. By continuously stirring the mixtures 4b and 5b in CH 2 Cl 2 solution for 2 h, complex 5b was formed as the final product. Complex [Pd(η 1 -SCNMe 2 )(η 2 -Phen)(Cl)] (6) or [Pd{η 1 -SC(O)NMe 2 }Pd(Cl)](μ,η 2 -SCNMe 2 )-(μ,η 2 -dppm) 2 (7) is accessible by the reaction of 1 with phen (1,10-phenanthroline) or dppm {bis(diphenyl-phosphino)methane} in dichloromethane at room temperature. All ofthe complexes are identified by spectroscopic methods and complexes 1, 3, 5a, and 7 are determined by single-crystal X-ray diffraction. The complexes 1 and 3 crystallize in the monoclinic space group P2 1 /n and P2,/c with Z= 4, respectively, whereas 5a and 7 belong to the triclinic space group P 1 with Z = 2. The cell dimensions are as follows: for 1, a = 12.8248(1) A, b = 18.6358(2) A, c = 14.9692(1) A, β = 105.1513(4)°; for 3, a = 9.8782(1) A, b = 11.7238(1) A, c = 20.7353(2) A, α = 103.9126(5)°, β = 97.8453(3)°, y = 104.9669(5)°; for 5a, a = 16.3638(2) A, b = 9.3374(1) A, c = 15.7117(2) A, β = 98.2957(6)°; for 7, α = 12.1128(1) A, b = 14.0133(2) A, c = 17.7873(2) A, α = 82.1939(5), β = 79.6190(6)°, y = 80.9551(5)°." @default.
- W2163118625 created "2016-06-24" @default.
- W2163118625 creator A5005938008 @default.
- W2163118625 creator A5032527585 @default.
- W2163118625 creator A5035862710 @default.
- W2163118625 creator A5036766053 @default.
- W2163118625 creator A5057574653 @default.
- W2163118625 date "2004-04-01" @default.
- W2163118625 modified "2023-09-23" @default.
- W2163118625 title "Synthesis, Dissociation Behavior and Crystal Structures of Palladium(II) Complexes with N,N-Dimethylthiocarbamoyl, Me2NC=S, Containing Ligand: Structures of [Pd(PPh3)2(η1-SCNMe2)(Cl)], [Pd(PPh3)(Cl)]2(μ,η2-SCNMe2)2, [Pd(PPh3)2{η1-C(SMe)(NMe2)}(η2-S2CO)]," @default.
- W2163118625 cites W1495608637 @default.
- W2163118625 cites W1533641059 @default.
- W2163118625 cites W1966152033 @default.
- W2163118625 cites W1973085105 @default.
- W2163118625 cites W1973258241 @default.
- W2163118625 cites W1980970756 @default.
- W2163118625 cites W1987802280 @default.
- W2163118625 cites W1990268970 @default.
- W2163118625 cites W1996775560 @default.
- W2163118625 cites W1998007561 @default.
- W2163118625 cites W2006157355 @default.
- W2163118625 cites W2018048682 @default.
- W2163118625 cites W2024616273 @default.
- W2163118625 cites W2025288192 @default.
- W2163118625 cites W2030436151 @default.
- W2163118625 cites W2034699189 @default.
- W2163118625 cites W2037874580 @default.
- W2163118625 cites W2038621792 @default.
- W2163118625 cites W2041097036 @default.
- W2163118625 cites W2043068345 @default.
- W2163118625 cites W2043124142 @default.
- W2163118625 cites W2047067464 @default.
- W2163118625 cites W2047522243 @default.
- W2163118625 cites W2048439844 @default.
- W2163118625 cites W2056596195 @default.
- W2163118625 cites W2060592150 @default.
- W2163118625 cites W2061605923 @default.
- W2163118625 cites W2062279703 @default.
- W2163118625 cites W2064267451 @default.
- W2163118625 cites W2071614883 @default.
- W2163118625 cites W2076399823 @default.
- W2163118625 cites W2078431099 @default.
- W2163118625 cites W2079890488 @default.
- W2163118625 cites W2094848559 @default.
- W2163118625 cites W2133385786 @default.
- W2163118625 cites W2140655863 @default.
- W2163118625 cites W2228617431 @default.
- W2163118625 cites W2949778478 @default.
- W2163118625 cites W2994441449 @default.
- W2163118625 cites W3137659925 @default.
- W2163118625 cites W3138249209 @default.
- W2163118625 doi "https://doi.org/10.1002/jccs.200400044" @default.
- W2163118625 hasPublicationYear "2004" @default.
- W2163118625 type Work @default.
- W2163118625 sameAs 2163118625 @default.
- W2163118625 citedByCount "12" @default.
- W2163118625 countsByYear W21631186252012 @default.
- W2163118625 countsByYear W21631186252018 @default.
- W2163118625 countsByYear W21631186252020 @default.
- W2163118625 crossrefType "journal-article" @default.
- W2163118625 hasAuthorship W2163118625A5005938008 @default.
- W2163118625 hasAuthorship W2163118625A5032527585 @default.
- W2163118625 hasAuthorship W2163118625A5035862710 @default.
- W2163118625 hasAuthorship W2163118625A5036766053 @default.
- W2163118625 hasAuthorship W2163118625A5057574653 @default.
- W2163118625 hasConcept C102931765 @default.
- W2163118625 hasConcept C115624301 @default.
- W2163118625 hasConcept C116569031 @default.
- W2163118625 hasConcept C155647269 @default.
- W2163118625 hasConcept C161790260 @default.
- W2163118625 hasConcept C170493617 @default.
- W2163118625 hasConcept C178790620 @default.
- W2163118625 hasConcept C185592680 @default.
- W2163118625 hasConcept C2777164566 @default.
- W2163118625 hasConcept C2777247709 @default.
- W2163118625 hasConcept C2778695967 @default.
- W2163118625 hasConcept C2780400988 @default.
- W2163118625 hasConcept C2780471494 @default.
- W2163118625 hasConcept C502130503 @default.
- W2163118625 hasConcept C55493867 @default.
- W2163118625 hasConcept C71240020 @default.
- W2163118625 hasConcept C75079739 @default.
- W2163118625 hasConcept C8010536 @default.
- W2163118625 hasConceptScore W2163118625C102931765 @default.
- W2163118625 hasConceptScore W2163118625C115624301 @default.
- W2163118625 hasConceptScore W2163118625C116569031 @default.
- W2163118625 hasConceptScore W2163118625C155647269 @default.
- W2163118625 hasConceptScore W2163118625C161790260 @default.
- W2163118625 hasConceptScore W2163118625C170493617 @default.
- W2163118625 hasConceptScore W2163118625C178790620 @default.
- W2163118625 hasConceptScore W2163118625C185592680 @default.
- W2163118625 hasConceptScore W2163118625C2777164566 @default.
- W2163118625 hasConceptScore W2163118625C2777247709 @default.
- W2163118625 hasConceptScore W2163118625C2778695967 @default.
- W2163118625 hasConceptScore W2163118625C2780400988 @default.
- W2163118625 hasConceptScore W2163118625C2780471494 @default.
- W2163118625 hasConceptScore W2163118625C502130503 @default.
- W2163118625 hasConceptScore W2163118625C55493867 @default.
- W2163118625 hasConceptScore W2163118625C71240020 @default.
- W2163118625 hasConceptScore W2163118625C75079739 @default.