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• W2163392783 abstract "Abstract A new Co complex of a unique diamidine ligand catalyzes asymmetric NaBH 4 reduction of C3‐disubstituted ( E )‐ and ( Z )‐2‐propenoates, including C3‐oxygen‐ and nitrogen‐substituted substrates with high enantioselectivity. Analysis by X‐ray diffraction, 1 H NMR spectroscopy, ring‐opening radical‐clock and D‐labeling reactions, and the structure/selectivity relationship suggest that a mechanism of CoH‐involved non‐single‐electron transfer 1,4‐addition differentiates the C2 enantioface. Involvement of CoH species has been supported by quantitative isolation of a new type of CoH 2 (BH 3 ) 2 complex." @default.
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• W2163392783 date "2015-04-27" @default.
• W2163392783 modified "2023-10-01" @default.
• W2163392783 title "Asymmetric NaBH₄1,4-Reduction of C3-Disubstituted 2-Propenoates Catalyzed by a Diamidine Cobalt Complex" @default.
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• W2163392783 doi "https://doi.org/10.1002/cctc.201500260" @default.
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