Matches in SemOpenAlex for { <https://semopenalex.org/work/W2163396657> ?p ?o ?g. }
Showing items 1 to 88 of
88
with 100 items per page.
- W2163396657 endingPage "171" @default.
- W2163396657 startingPage "161" @default.
- W2163396657 abstract "The hydrogenation of the complexes [RuCl3(DPA)] 1, [Ru(SnCl3)-Cl2(DPA)]2, [RuCl2(DPA)2]Cl 3, [Ru(SnCl3)Cl(DPA)2]Cl 4, [RuCl2(PPh3)-(DPA)] 5, [Ru(SnCl3)Cl(PPh3)(DPA)] 6, [RuCl(DMSO)2(DPA)]Cl 7 and [Ru(SnCl3)(DMSO)2(DPA)]Cl 8, where DPA = HN(CH2CH2PPh2)2 show the formation of hydrides in benzene-ethanol and 1 atm of H2 at 30 °C in situ, as confirmed by 1H NMR spectra. The homogeneous hydrogenation of cyclohexene catalysed by the above complexes was studied at 30 °C and 1 atm of molecular hydrogen in benzene-ethanol mixture. A mechanism for the homogeneous hydrogenation reaction is proposed where the coordination of the olefin to the hydride complex is rate determining, followed by a rapid transfer of the hydrogen to the olefin to form the alkane. The ratio of the equilibrium constants K2/K1 for the formation of olefin/hydrido complex and the rate constant k (rate-determining step) were calculated and reported. The variation of the rates for catalytic hydro-genation of cyclohexene with the nature of the catalyst is discussed." @default.
- W2163396657 created "2016-06-24" @default.
- W2163396657 creator A5056012165 @default.
- W2163396657 creator A5067078331 @default.
- W2163396657 date "1987-10-01" @default.
- W2163396657 modified "2023-09-29" @default.
- W2163396657 title "Homogeneous hydrogenation of cyclohexene catalyzed by Ru(II) and (III) and their trichloro-stannato complexes: Proton NMR and rate studies" @default.
- W2163396657 cites W1992482809 @default.
- W2163396657 cites W1996310246 @default.
- W2163396657 cites W2001794100 @default.
- W2163396657 cites W2020752830 @default.
- W2163396657 cites W2027791580 @default.
- W2163396657 cites W2028746038 @default.
- W2163396657 cites W2052685540 @default.
- W2163396657 cites W2060180921 @default.
- W2163396657 cites W2148736127 @default.
- W2163396657 cites W2151592003 @default.
- W2163396657 cites W2165641155 @default.
- W2163396657 cites W2319007066 @default.
- W2163396657 cites W2345354405 @default.
- W2163396657 cites W2604756279 @default.
- W2163396657 cites W3139020242 @default.
- W2163396657 cites W4235639095 @default.
- W2163396657 doi "https://doi.org/10.1016/0304-5102(87)85022-8" @default.
- W2163396657 hasPublicationYear "1987" @default.
- W2163396657 type Work @default.
- W2163396657 sameAs 2163396657 @default.
- W2163396657 citedByCount "7" @default.
- W2163396657 countsByYear W21633966572012 @default.
- W2163396657 countsByYear W21633966572019 @default.
- W2163396657 crossrefType "journal-article" @default.
- W2163396657 hasAuthorship W2163396657A5056012165 @default.
- W2163396657 hasAuthorship W2163396657A5067078331 @default.
- W2163396657 hasConcept C109474758 @default.
- W2163396657 hasConcept C121332964 @default.
- W2163396657 hasConcept C147789679 @default.
- W2163396657 hasConcept C148898269 @default.
- W2163396657 hasConcept C155647269 @default.
- W2163396657 hasConcept C161790260 @default.
- W2163396657 hasConcept C178790620 @default.
- W2163396657 hasConcept C179104552 @default.
- W2163396657 hasConcept C185592680 @default.
- W2163396657 hasConcept C2777691172 @default.
- W2163396657 hasConcept C2777961443 @default.
- W2163396657 hasConcept C2779484182 @default.
- W2163396657 hasConcept C512968161 @default.
- W2163396657 hasConcept C51886252 @default.
- W2163396657 hasConcept C62520636 @default.
- W2163396657 hasConcept C75473681 @default.
- W2163396657 hasConcept C93391505 @default.
- W2163396657 hasConceptScore W2163396657C109474758 @default.
- W2163396657 hasConceptScore W2163396657C121332964 @default.
- W2163396657 hasConceptScore W2163396657C147789679 @default.
- W2163396657 hasConceptScore W2163396657C148898269 @default.
- W2163396657 hasConceptScore W2163396657C155647269 @default.
- W2163396657 hasConceptScore W2163396657C161790260 @default.
- W2163396657 hasConceptScore W2163396657C178790620 @default.
- W2163396657 hasConceptScore W2163396657C179104552 @default.
- W2163396657 hasConceptScore W2163396657C185592680 @default.
- W2163396657 hasConceptScore W2163396657C2777691172 @default.
- W2163396657 hasConceptScore W2163396657C2777961443 @default.
- W2163396657 hasConceptScore W2163396657C2779484182 @default.
- W2163396657 hasConceptScore W2163396657C512968161 @default.
- W2163396657 hasConceptScore W2163396657C51886252 @default.
- W2163396657 hasConceptScore W2163396657C62520636 @default.
- W2163396657 hasConceptScore W2163396657C75473681 @default.
- W2163396657 hasConceptScore W2163396657C93391505 @default.
- W2163396657 hasIssue "2" @default.
- W2163396657 hasLocation W21633966571 @default.
- W2163396657 hasOpenAccess W2163396657 @default.
- W2163396657 hasPrimaryLocation W21633966571 @default.
- W2163396657 hasRelatedWork W1510441155 @default.
- W2163396657 hasRelatedWork W1963558580 @default.
- W2163396657 hasRelatedWork W1971986412 @default.
- W2163396657 hasRelatedWork W2035823835 @default.
- W2163396657 hasRelatedWork W2043015059 @default.
- W2163396657 hasRelatedWork W2085546634 @default.
- W2163396657 hasRelatedWork W2131998450 @default.
- W2163396657 hasRelatedWork W2381450934 @default.
- W2163396657 hasRelatedWork W2391783161 @default.
- W2163396657 hasRelatedWork W2801974292 @default.
- W2163396657 hasVolume "42" @default.
- W2163396657 isParatext "false" @default.
- W2163396657 isRetracted "false" @default.
- W2163396657 magId "2163396657" @default.
- W2163396657 workType "article" @default.