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- W2163440277 abstract "Abstract Neue Strukturmotive für Organosuperbasen, die leicht zugänglich sind und hohe Basizitäten aufweisen, sind für viele Bereiche der Chemie dringend notwendig. Wir berichten hier über die Synthese von N,N′‐ B is( i midazolyl) g uanidin‐Basen (BIG‐Basen). Ihre pK α ‐Werte wurden zu 26.1–29.3 in THF bestimmt. Sie sind damit wahrscheinlich die stärksten phosphorfreien organischen Basen sowohl in Lösung als auch in der Gasphase. Rechnungen halfen bei der Bestimmung der strukturellen und elektronischen Faktoren, die zur beobachteten hohen Basizität beitragen." @default.
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- W2163440277 date "2013-12-13" @default.
- W2163440277 modified "2023-10-18" @default.
- W2163440277 title "Sehr starke Organosuperbasen durch Verknüpfung von Imidazol- und Guanidinbasen - Synthese, Struktur und Basizität" @default.
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- W2163440277 doi "https://doi.org/10.1002/ange.201307212" @default.
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