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- W2163471915 abstract "Ring opening reaction of α-epoxyketones in the presence of DDQ in methanol solution under microwave and UV irradiations results in the formation of α-hydroxy-β-methoxyketones through C β –O bond cleavage in excellent yields. Whereas the nature and location of the additional substituent affect the rate of ring opening, microwave irradiation remarkably raises the rate of reactions compared with UV-light. Cyclic voltammetric and conductometric studies support these experimental results. Ring opening reaction of α-epoxyketones in the presence of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone in methanol solution under microwave and UV irradiations resulted in the formation of α-hydroxy-β-methoxyketones through C β –O bond cleavage in excellent yields. Whereas the nature and location of the additional substituent affect the rate of ring opening, microwave irradiation remarkably raised the rate of reactions compared with UV-light. Cyclic voltammetric and conductometric studies supported these experimental results." @default.
- W2163471915 created "2016-06-24" @default.
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- W2163471915 date "2007-09-01" @default.
- W2163471915 modified "2023-10-18" @default.
- W2163471915 title "Microwave-assisted and light-induced catalytic ring opening of α-epoxyketones using DDQ" @default.
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- W2163471915 doi "https://doi.org/10.1016/j.molcata.2007.05.010" @default.
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