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- W2163592031 abstract "Chiral organoaluminum complex 1 efficiently catalyzed the asymmetric hetero-ene reaction of commercially available 2-methoxypropene (2) with aldehydes under mild conditions to give the corresponding β-hydroxymethyl ketones 3 in good to excellent chemical yields with high enantiomeric excesses. The asymmetric catalysis of 1 was further applied to the carbonyl addition of methallylsilanes, where exclusive formation of the optically active allylic silanes 5 was achieved." @default.
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- W2163592031 date "2004-05-01" @default.
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- W2163592031 title "Efficient asymmetric catalysis of chiral organoaluminum complex for enantioselective ene reactions of aldehydes" @default.
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- W2163592031 doi "https://doi.org/10.1016/j.tetlet.2004.04.052" @default.
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