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- W2163599723 abstract "High molecular weight poly(vinyl)silazane were synthesized successfully by reversible addition fragmentation chain transfer (RAFT) polymerization in toluene at 120 °C, using dithiocarbamate derivatives and 2,2'-azobis-isobutyrylnitrile (AIBN) as the RAFT agents and thermal initiator, respectively. The polymerization of a vinylcyclicsilazane oligomer with 82.5% conversion was readily controlled to increase the molecular weight from 1000 to 12,000 g/mol with a narrow polydispersity <1.5. The resulting polymer showed a high ceramic yield of 70 wt % at 1000 °C. Moreover, the approach was extended successfully to the synthesis of poly(vinyl)silazane-block-polystyrene as an inorganic-organic diblock copolymer." @default.
- W2163599723 created "2016-06-24" @default.
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- W2163599723 date "2008-01-01" @default.
- W2163599723 modified "2023-09-24" @default.
- W2163599723 title "Controlled/living radical polymerization of vinylcyclicsilazane by RAFT process and their block copolymers" @default.
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- W2163599723 doi "https://doi.org/10.1002/pola.22804" @default.
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