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• W2163796746 abstract "Oxyanion substitution of enyne-allenes causes both Myers−Saito and Schmittel cyclizations to switch their product formation preferences from diradicals to polar, closed-shell singlets. The oxyanion stabilization is larger for the Schmittel products than the Myers−Saito products because the latter must sacrifice aromaticity to maximize interaction. The changing character of the different reaction paths is reflected in their activation energies." @default.
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• W2163796746 date "2001-05-16" @default.
• W2163796746 modified "2023-10-16" @default.
• W2163796746 title "Biradical and Zwitterionic Cyclizations of Oxy-Substituted Enyne-Allenes" @default.
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• W2163796746 doi "https://doi.org/10.1021/ol015935e" @default.
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