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- W2163856475 abstract "Mononuclear high-spin [FeIII(Pyimpy)Cl3]⋅2 CH2Cl2 (1⋅2 CH2Cl2) and [FeIII(Me-Pyimpy)Cl3] (2), as well as low-spin FeII(Pyimpy)2](ClO4)2 (3) and [FeII(Me-Pyimpy)2](ClO4)2 (4) complexes of tridentate ligands Pyimpy and Me-Pyimpy have been synthesized and characterized by analytical techniques, spectral, and X-ray structural analyses. We observed an important type of conversion and associated spontaneous reduction of mono-chelated high-spin FeIII (1⋅2 CH2Cl2 and 2) complexes to low-spin bis-chelated FeII complexes 3 and 4, respectively. This process has been explored in detail by UV/Vis, fluorescence, and 1H NMR spectroscopic measurements. The high positive potentials observed in electrochemical studies suggested a better stabilization of FeII centers in 3 and 4. Theoretical studies by density functional theory (DFT) calculations supported an increased stabilization for 3 in polar solvents. Self-activated nuclease activity of complexes 1⋅2CH2Cl2 and 2 during their spontaneous reduction was examined for the first time and the mechanism of nuclease activity was investigated." @default.
- W2163856475 created "2016-06-24" @default.
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- W2163856475 date "2014-12-08" @default.
- W2163856475 modified "2023-10-14" @default.
- W2163856475 title "Spontaneous Reduction of Mononuclear High-Spin Iron(III) Complexes to Mononuclear Low-Spin Iron(II) Complexes in Aqueous Media and Nuclease Activity via Self-Activation" @default.
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- W2163856475 doi "https://doi.org/10.1002/asia.201402954" @default.
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