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• W2164247174 abstract "High resolution Fourier transform infrared emission spectra of MgH and MgD have been recorded. The molecules were generated in an emission source that combines an electrical discharge with a high temperature furnace. Several vibration–rotation bands were observed for all six isotopomers in the X 2Σ+ ground electronic state: v=1→0 to 4→3 for MgH24, v=1→0 to 3→2 for MgH25 and MgH26, v=1→0 to 5→4 for MgD24, v=1→0 to 4→3 for MgD25 and MgD26. The new data were combined with the previous ground state data, obtained from diode laser vibration–rotation measurements and pure rotation spectra, and spectroscopic constants were determined for the v=0 to 4 levels of MgH24 and the v=0 to 5 levels of MgD24. In addition, Dunham constants and Born–Oppenheimer breakdown correction parameters were obtained in a combined fit of the six isotopomers. The equilibrium vibrational constants (ωe) for MgH24 and MgD24 were found to be 1492.776(7) cm−1 and 1077.298(5) cm−1, respectively, while the equilibrium rotational constants (Be) are 5.825 523(8) cm−1 and 3.034 344(4) cm−1. The associated equilibrium bond distances (re) were determined to be 1.729 721(1) Å for MgH24 and 1.729 157(1) Å for MgD24." @default.
• W2164247174 created "2016-06-24" @default.
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• W2164247174 date "2004-05-11" @default.
• W2164247174 modified "2023-09-23" @default.
• W2164247174 title "Fourier transform infrared emission spectra of MgH and MgD" @default.
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• W2164247174 doi "https://doi.org/10.1063/1.1724821" @default.
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