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- W2164443306 abstract "Phase equilibria in the TaNiO and NbNiO systems were studied at 1200°C at oxygen partial pressures ranging from 1 to 10−12.00 atm in the TaNiO system and from 1 to 10−14.50 atm in the NbNiO system. The NiO system was reinvestigated to confirm the previous data and to check the experimental method. In both systems Ta2NiO6 and Nb2NiO6 are stable ternary compounds under the present experimental conditions; the former has a small compositional width and the latter is almost stoichiometric. Nb2Ni3O8 and Nb2Ni4O9 are not stable. Lattice constants of the ternary compounds were obtained for the quenched samples. The standard Gibbs energies of the reaction M2O5 + Ni + 12O2 = M2NiO6 were also determined from the oxygen partial pressures in equilibrium with three solids." @default.
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- W2164443306 date "1989-11-01" @default.
- W2164443306 modified "2023-09-23" @default.
- W2164443306 title "Thermogravimetric study of the MNiO system. I. M = Ta and Nb" @default.
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- W2164443306 doi "https://doi.org/10.1016/0022-4596(89)90051-0" @default.
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