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- W2164515900 abstract "The phenomenon of intermediate valence (IV) has recently received a good deal of experimental and theoretical attention, but in spite of all the effort the phenomenon is not well understood, particularly the low temperature observations. The theoretical situation is reviewed, and those areas where the understanding seems to be reasonably satisfactory and also those where it is less satisfactory are delineated. The topic is introduced through a simple description of IV. This is followed by a brief account of some of the experimental results from which it is seen that while there are some phenomena which can be understood in an elementary way, there are others which are quite puzzling. A more detailed study is then made of the type of Hamiltonian which it would seem appropriate to use, and this is followed by an account of the approximations which have been used reasonably successfully (thermodynamic-type treatments and high-temperature thermodynamic perturbation theory). Attention is focused on the problem of the ground- and low-lying energy levels." @default.
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- W2164515900 date "1978-10-14" @default.
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- W2164515900 title "Intermediate valence-a view of the theoretical situation" @default.
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- W2164515900 doi "https://doi.org/10.1088/0022-3719/11/19/006" @default.
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