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- W2164534995 abstract "The oxidation of gaseous glyoxal has been studied at temperatures between 290 and 370 °C both manometrically and by detailed product analysis. The reaction has been shown to occur in two stages; in the first, glyoxal reacts to give mainly carbon monoxide and glyoxalic acid and in the second, glyoxalic acid is subject to further oxidation to oxalic acid, hydrogen peroxide, carbon dioxide and water. Of the two previous investigations of the reaction, that of Steacie, Hatcher & Horwood (1935 a ) has been shown to have been concerned with the first stage and in the other (Newitt, Baxt & Kelkar 1939), carried out at ignition temperatures, the reaction proceeded through both stages. The oxidation is accompanied by an oxygen induced decomposition and a mechanism similar to that proposed by one of us (Axford & Norrish 1948) for the oxidation of formaldehyde, involving OH, CHO and HO 2 radicals has been developed and shown to account satisfactorily for the observed facts." @default.
- W2164534995 created "2016-06-24" @default.
- W2164534995 date "1965-10-05" @default.
- W2164534995 modified "2023-10-18" @default.
- W2164534995 title "The oxidation of gaseous glyoxal" @default.
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- W2164534995 doi "https://doi.org/10.1098/rspa.1965.0197" @default.
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