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- W2164581750 abstract "Tetraaqua(18-crown-6)cerium(III) hexacyanoferrate(III) dihydrate, [Ce(C12H24O6)(H2O)4][Fe(CN)6]·2H2O, and tetraaqua(18-crown-6)neodymium(III) hexacyanoferrate(III) dihydrate, [Nd(C12H24O6)(H2O)4][Fe(CN)6]·2H2O, are isomorphous and isostructural in the C2/c space group, where the cations, which contain ten-coordinate lanthanoid centres, lie across twofold rotation axes and the anions lie across inversion centres. In these compounds, an extensive series of O—H⋯O and O—H⋯N hydrogen bonds links the components into a continuous three-dimensional framework. Triaqua(18-crown-6)lanthanoid(III) hexacyanoferrate(III) dihydrate, [Ln(C12H24O6)(H2O)3][Fe(CN)6]·2H2O, where Ln = Sm, Eu, Gd or Tb, are all isomorphous and isostructural in the Poverline{1} space group, as are triaqua(18-crown-6)gadolinium(III) hexacyanochromate(III) dihydrate, [Gd(C12H24O6)(H2O)3][Cr(CN)6]·2H2O, and triaqua(18-crown-6)gadolinium(III) hexacyanocobaltate(III) dihydrate, [Gd(C12H24O6)(H2O)3][Co(CN)6]·2H2O. In these compounds, there are two independent anions, both lying across inversion centres, and the lanthanoid centres exhibit nine-coordination; in the crystal structures, an extensive series of hydrogen bonds links the components into a three-dimensional framework." @default.
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- W2164581750 date "2007-09-01" @default.
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- W2164581750 title "Hydrated hexacyanometallate(III) salts of triaqua(18-crown-6)lanthanoid(III) and tetraaqua(18-crown-6)lanthanoid(III) cations containing nine- and ten-coordinate lanthanoids" @default.
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- W2164581750 doi "https://doi.org/10.1107/s0108270107040449" @default.
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