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• W2164616089 endingPage "1402" @default.
• W2164616089 startingPage "1396" @default.
• W2164616089 abstract "ABSTRACT Palladium‐catalyzed direct arylation polycondensation afforded a bithiazole‐based homopolymer and donor–acceptor (D–A)‐type copolymers where the bithiazole unit served as an acceptor unit. The results of polymerization strongly depended on the solubility of the polymers; long alkyl chain substituents were required for the formation of high‐molecular‐weight polymers in high yields owing to low solubility of the bithiazole‐based polymers. X‐ray diffraction studies revealed that the obtained polymers were highly crystalline. In particular, a well‐ordered lamellar structure was observed in the D–A‐type copolymer with flexible alkyl chains after thermal annealing, presumably owing to the combination of interchain interactions between the bithiazole units and the electrostatic D–A interactions. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53 , 1396–1402" @default.
• W2164616089 created "2016-06-24" @default.
• W2164616089 creator A5000177548 @default.
• W2164616089 creator A5016293152 @default.
• W2164616089 creator A5022742877 @default.
• W2164616089 creator A5048830169 @default.
• W2164616089 date "2015-03-23" @default.
• W2164616089 modified "2023-10-06" @default.
• W2164616089 title "Synthesis of bithiazole-based crystalline polymers via palladium-catalyzed direct CH arylation" @default.
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• W2164616089 doi "https://doi.org/10.1002/pola.27611" @default.

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