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• W2164641010 abstract "Slow diffusion of aqueous cobalt thiocyanate or cadmium perchlorate and ethanolic solutions of 3,4′-dipyridylketone (3,4′-dpk) generated the coordination polymers {[Co(NCS)2(3,4′-dpk)2]·2H2O}n (1) and {[Cd(H2O)2(3,4′-dpk)2](ClO4)2·2H2O}n (2), which were structurally characterized by single-crystal X-ray diffraction. The structure of 1 consists of interdigitated neutral [Co(NCS)2(3,4′-dpk)2]n (4,4) rectangular grid coordination polymer layers. However, compound 2 manifests cationic [Cd(H2O)2(3,4′-dpk)2]n2n+ two-dimensional (6,3) herringbone lattices connected through hydrogen bonding mediated by interlamellar unligated perchlorate anions. Upon excitation with ultraviolet radiation, 2 emits blue-violet light, ascribed to π–π* transitions within the pyridyl rings of the 3,4′-dpk ligands. Thermal decomposition behavior of 1 is also discussed." @default.
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• W2164641010 date "2009-09-01" @default.
• W2164641010 modified "2023-09-25" @default.
• W2164641010 title "Two-Dimensional Divalent Metal Coordination Polymers Containing 3,4′-Dipyridylketone Tethers: Layer Topology Tuning by Anion Binding Preferences" @default.
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• W2164641010 doi "https://doi.org/10.1002/zaac.200900150" @default.
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