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• W2164843911 abstract "Iodine was found to be an efficient catalyst for the aziridination of alkenes utilizing Chloramine-T (N-chloro-N-sodio-p-toluenesulfonamide) as a nitrogen source. For example, when two equivalents of styrene were added to Chloramine-T in the presence of a catalytic amount of iodine in a 1 : 1 solvent mixture of acetonitrile and neutral buffer, the corresponding aziridine 1 was obtained in 91% yield. The reaction could be applied to other acyclic and cyclic alkenes such as 1-octene and cyclohexene. The aziridination of p-substituted styrene derivatives 2–5 with Chloramine-T showed that electron-rich alkenes reacted faster than electron-poor ones. Several Chloramine-T analogs were also examined and were found to give the corresponding aziridines 8–10 in only moderate yields." @default.
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• W2164843911 date "1998-10-01" @default.
• W2164843911 modified "2023-10-18" @default.
• W2164843911 title "Iodine-catalyzed aziridination of alkenes using Chloramine-T as a nitrogen source" @default.
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• W2164843911 doi "https://doi.org/10.1016/s0040-4020(98)00827-8" @default.
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