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- W2164961037 endingPage "8833" @default.
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- W2164961037 abstract "Proceed with caution: The use of fluoride starting materials and SO2 as a solvent yields neat triazides M(N3)3 (M=Ga, In, Tl), thus firmly establishing the existence of thallium triazide. In CH3CN, the new M(N3)3⋅CH3CN donor–acceptor adducts were obtained. Reactions of the triazides with tetraphenylphosphonium azide in CH3CN yields exclusively the novel [Ga(N3)5]2−, [In(N3)6]3− and [Tl(N3)6]3− anions (see picture, M green, N blue)." @default.
- W2164961037 created "2016-06-24" @default.
- W2164961037 creator A5030527991 @default.
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- W2164961037 date "2011-07-15" @default.
- W2164961037 modified "2023-10-18" @default.
- W2164961037 title "Preparation and Characterization of the Binary Group 13 Azides M(N3)3 and M(N3)3⋅CH3CN (M=Ga, In, Tl), [Ga(N3)5]2−, and [M(N3)6]3− (M=In, Tl)" @default.
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- W2164961037 doi "https://doi.org/10.1002/anie.201103101" @default.
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