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- W2164999709 abstract "Radiolysis free ion yields were measured as a function of electric-field strength in vapor/liquid equilibrium fluids of ethene, propene, cyclopropane, propane, n-butane and i-butane at 0.15<or=d/d/sub c/<3(d/sub c/=critical fluid density). From these yields, secondary electron thermalization distances b/sub GP/ were estimated using the extended Onsager model. In the normal liquid at d/d/sub c/>1.5, the effects of molecular shape gave b/sub GP/d in methane>i-butane>ethane>propane>n-butane. The effect of pi -bonding gave n-butane>cyclopropane>ethene approximately propene; the permanent dipole of propene had negligible effect in the dense liquid. The conduction-band energy in supercritical fluids of n-butane, isobutane, n-pentane and isopentane was measured as a function of the fluid density. The conduction-band energy values in these fields show a density dependence that is related to their molecular structure. The correlation between the density dependence of conduction-band energy and of electron mobility is discussed in terms of the deformation potential theory.<<ETX>>" @default.
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- W2164999709 date "1988-01-01" @default.
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- W2164999709 title "Electron thermalization distances and free ion yields in dense gases and liquids-effects of molecular structure" @default.
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- W2164999709 doi "https://doi.org/10.1109/14.7318" @default.
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