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- W2165087003 abstract "The ultrafast dynamics of the dissociation of M(CO)6 (M = Cr, W, Mo) in alkane solutions were studied by femtosecond IR spectroscopy. After UV photolysis at 295 nm, both the bleach of the parent molecules and the absorption of the pentacarbonyl intermediate were probed with 240 fs time resolution. Oscillatory perturbed free induction decay signals before t = 0 were observed and well characterized by realistic parameters of the system. The bleach recovery dynamics were found to be wavelength dependent, indicating that hot parent molecules are formed and that the bleach recovery time is determined by the vibrational cooling time. The measured percentage bleach recovery in n-heptane is less than the expected value calculated from the photosubstitution quantum yield measurements, suggesting that the initial recovery of the bleach is faster than our time resolution. The kinetics in the A1 vibrational mode region of the pentacarbonyl species have been measured to probe the formation and decay of the nascent pro..." @default.
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- W2165087003 date "1996-01-01" @default.
- W2165087003 modified "2023-10-17" @default.
- W2165087003 title "Femtosecond Infrared Studies of the Dissociation and Dynamics of Transition Metal Carbonyls in Solution" @default.
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- W2165087003 doi "https://doi.org/10.1021/jp9618035" @default.
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