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- W2165120552 abstract "The direct visualization of micelle transitions is a long-standing challenge owing to the intractable aggregation-caused quenching of light emission in the micelle solution. Herein, we report the synthesis of a surfactant with a tetraphenylethene (TPE) core and aggregation-induced emission (AIE) characteristics. The transition processes of surfactant micelles and the microemulsion droplets (MEDs) formed by the surfactant with a TPE core were clearly visualized by a high-contrast fluorescence imaging method. The fluorescence intensity of the MEDs decreased as the size of MEDs increased as a result of weakening of the restriction of intramolecular rotation (RIR). The results of this study deepen our understanding of micelle-transition processes and provide solid evidence in favor of the hypothesis that the AIE phenomenon has its origin in the RIR of fluorophores in the aggregate state." @default.
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- W2165120552 date "2015-10-16" @default.
- W2165120552 modified "2023-10-16" @default.
- W2165120552 title "Synthesis and Design of Aggregation-Induced Emission Surfactants: Direct Observation of Micelle Transitions and Microemulsion Droplets" @default.
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- W2165120552 doi "https://doi.org/10.1002/anie.201507236" @default.
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