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- W2165175393 abstract "A capillary electrophoresis (CE) with UV absorption detection method is described for the simultaneous determination of glufosinate, glyphosate, and aminomethylphosphoric acid. The 9-fluorenylmethyl chloroformate (FMOC-Cl) was used for precolumn derivatization of the non-absorbing herbicides. The three analytes were separated by CE in 9 min with 25 mM borate buffer at pH 9, followed by detection with a UV detector at 260 nm. We demonstrate how the detection limit can be enhanced by using acetonitrile-salt mixtures. With acetonitrile-salt mixtures, the limit of detection (LOD) was in the 10−7 M range. Linearity of more than two orders of magnitude was generally obtained. Precisions of migration times and peak areas were less than 0.9% and 7.5%, respectively. The applicabilities of the method for the analysis of ground water and lake water were examined." @default.
- W2165175393 created "2016-06-24" @default.
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- W2165175393 date "2005-08-01" @default.
- W2165175393 modified "2023-10-14" @default.
- W2165175393 title "Simultaneous Determination of Glyphosate, Glufosinate, and Aminomethylphosphonic Acid by Capillary Electrophoresis After 9-Fluorenylmethyl Chloroformate Derivatization" @default.
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- W2165175393 doi "https://doi.org/10.1002/jccs.200500110" @default.
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