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- W2165200707 abstract "The active sites for selective oxidation can be synthesized on polyoxometalates (oxide clusters). For example, Keggin-type di-iron-substituted silicotungstate, γ-SiW10 {Fe (OH2)} 20386- (I), was synthesized by the reaction of the lacunary γ-SiW10O368-with Fe (NO3) 3, in an acidic aqueous solution and isolated as the tetra-n-butylammonium salt (TBA-I). It was characterized by various analyses and the structure with the oxo-bridged di-iron site was clarified. TBA- I was stable and catalyzed selective oxidation of various alkanes and alkenes with hydrogen peroxide: Cyclohexane, adamantane, n-hexane, and n-pentane were catalytically oxidized. Even lower alkanes such as methane, ethane, propane, and n-butane were catalytically oxidized. It was remarkable that the efficiency of hydrogen peroxide utilization to oxygenated products reached up to ca. 100% for the oxidation of cyclohexane and adamantane. Alkenes were mainly epoxidized with hydrogen peroxide. In addition, it was demonstrated that the TBA-I showed high turnover numbers for the oxygenation of cyclohexane and epoxidation of alkenes with 1 atm oxygen." @default.
- W2165200707 created "2016-06-24" @default.
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- W2165200707 date "2003-02-18" @default.
- W2165200707 modified "2023-10-02" @default.
- W2165200707 title "Control of Structure of Oxide Cluster and the Application to Catalytic Technology." @default.
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- W2165200707 doi "https://doi.org/10.1002/chin.200307192" @default.
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