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- W2165264108 abstract "A kinetic study of the decomposition reaction of 1,4-dinitro-2-methylpyrrole (NMP) and ethylnitrolic acid (ENA), both formed in the reaction between sorbic acid and sodium nitrite was performed in the 3.5–4.2 pH range in water/dioxane mixtures. Conclusions were drawn as follows: (i) The decomposition of NMP occurs through nucleophilic attack by OH− ions, the rate equation being: r = kdecNMP [OH− ][NMP]. (ii) The rate law for the decomposition of ENA is: r = [ENA]Ka/(Ka + [H+]), Ka being the ENA dissociation constant. (iii) The value of Ka decreases when the water/dioxane ratio decreases, log Ka being proportional to the Onsager parameter (ϵ − 1)/(2ϵ + 1). This permits the equilibrium between non-dissociated and the dissociated forms of ENA to be rationalized. (iv) No appreciable variation in the ΔH# and ΔS# values with composition of the medium was observed, either in the NMP decomposition reaction, or in the ENA decomposition reaction. Copyright © 2008 John Wiley & Sons, Ltd." @default.
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- W2165264108 date "2009-05-01" @default.
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- W2165264108 title "Solvent effects in the decomposition reaction of some products formed by the reaction of sorbic acid with sodium nitrite: 1,4-dinitro-2-methylpyrrole and ethylnitrolic acid" @default.
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- W2165264108 doi "https://doi.org/10.1002/poc.1477" @default.
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