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- W2165364875 abstract "A convenient synthetic approach towards alkyloxy substituted (24-crown-8)-linked dimeric phthalocyanines is developed. The influence of the alteration of the reaction conditions and the origin of the precursors onto the yield of the target compounds is revealed. The Mg-templated statistical condensation of the mixture of phthalonitriles is found to be the most efficient and versatile pathway. The developed demetallation procedure of obtained Mg-phthalocyanines allows to prepare metal-free (24-crown-8)-linked dimeric phthalocyanines, which are versatile precursors for preparation of other metal complexes. The preliminary AM1 semi-empirical calculations have demonstrated that the dimeric linked phthalocyanine metal complexes may become convenient receptors for recognition of ditopic guests." @default.
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- W2165364875 date "2014-01-01" @default.
- W2165364875 modified "2023-10-03" @default.
- W2165364875 title "(24-Сrown-8)-Linked Dimeric Phthalocyanines and Their Metal Complexes" @default.
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- W2165364875 doi "https://doi.org/10.6060/mhc140508b" @default.
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