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- W2165514143 abstract "Telomerization of vinyl chloride with carbon tetrachloride was investigated in reaction systems containing amines and cupric chloride. The yield of telomers CCl3(CH2CHCl)nCl and the content of the telomer with n=1 were high when aliphatic amines with relatively long chains were used. An increase in basicity of amines raised the yield of telomers. When bifunctional amines such as diamines and alkanolamines were used, the yield of telomers was low and the content of higher telomers was high. The effect of added solvents on the yield of telomers was not so remarkable and an increase in the dielectric constant of solvents decreased the yields. The results were examined on the basis of Asscher-Vofsi mechanism, but could not be explained satisfactorily. A partly modified scheme was proposed for the radical addition in the cage complex stabilized with amine." @default.
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- W2165514143 date "1970-04-01" @default.
- W2165514143 modified "2023-10-03" @default.
- W2165514143 title "Telomerization of Vinyl Chloride with Carbon Tetrachloride Using Amine-Cupric Chloride. Effects of Amines and Solvents" @default.
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- W2165514143 doi "https://doi.org/10.1246/bcsj.43.1127" @default.
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