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- W2165655126 abstract "Although Rh(I)Cl(CO)(cpd) (cpd = cyclopentadienone) complexes were identified more than 40 years ago, their exact structures have not been determined because of the polymeric nature of these complexes. We determined the structure of [Rh(I)Cl(CO)(cpd)]2, which was formed by the reaction of [Rh(cod)Cl]2 with a 1,6-diyne under CO. In addition, based on determination of the structure of the [Rh(I)Cl(CO)(cpd)]2 complex, we identified a new catalytic tandem reaction—the Rh-catalyzed [2+2+1] carbonylative cycloaddition of phenoxide-substituted diynes and Claisen rearrangement." @default.
- W2165655126 created "2016-06-24" @default.
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- W2165655126 date "2010-01-01" @default.
- W2165655126 modified "2023-09-27" @default.
- W2165655126 title "Synthesis of [RhCl(CO)(cyclopentadienone)]2 from [RhCl(cod)]2 and a 1,6-diyne under CO: application to Rh(i)-catalyzed tandem [2+2+1] carbonylative cycloaddition of diynes and Claisen rearrangement" @default.
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- W2165655126 doi "https://doi.org/10.1039/c000747a" @default.
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