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- W2165837969 abstract "C-3 alkylation of coumarins has been accomplished using cycloalkanes or alkylbenzenes in the presence of di-tert-butylperoxide (DTBP) and Fe(III) catalyst. Under metal free conditions and just by switching the oxidant from DTBP to TBHP, an exclusive C-4 cycloalkylation-C-3 peroxidation reaction takes place. During C-3 alkylation, the C-C bond formation occurs at the expense of an existing C-C bond, while the C-4 alkylation is associated with the formation of new C-C and C-O bonds." @default.
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- W2165837969 date "2015-01-01" @default.
- W2165837969 modified "2023-10-06" @default.
- W2165837969 title "Oxidant controlled regioselective mono- and di-functionalization reactions of coumarins" @default.
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- W2165837969 doi "https://doi.org/10.1039/c5cc06200d" @default.
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